(85) Some Reactions of Monofluoroacetic Acid Derivatives.
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Stereoselective radical reactions of some tartaric and glyceric acid derivatives.
[reaction: see text] Free radicals generated by the decarboxylation of dimethoxydioxanecarboxylic acids derived from L-(+)-tartaric acid and L-glyceric acid added to some maleimides and acrylates with high stereoselectivity. This method provides easy access to some chiral building blocks.
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This is probably the single most important reaction of carboxylic acid derivatives. The overall transformation is defined by the following equation, and may be classified either as nucleophilic substitution at an acyl group or as acylation of a nucleophile. For certain nucleophilic reagents the reaction may assume other names as well. If Nuc-H is water the reaction is often called hydrolysis, i...
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Dixon, M. (1953). Biochem. J. 55, 161. Hacobian, S. (1953). Au8t. J. Chem. 6, 211. Keilin, D. & Hartree, E. F. (1939). Proc. Roy. Soc. B, 127, 167. Keilin, D. & Hartree, E. F. (1953). Nature, Lond., 171, 413. Kolthoff, I. M. & Jordan, J. (1952). Analyt. Chem. 24, 1071. Longmuir, I. S. (1954). Biochem. J. 57, 81. Moss, F. (1954). AuWt. J. exp. Biol. med. Sci. 32, 571. Slater, E. (1952). Biochem....
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1955
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.58.224